En synthèse organique : élaboration de stratégie générale pour la synthèse de molécules polycycliques naturelles et non-naturelles apparentées aux stéroïdes et terpènes.
Étude de la réaction de Diels-Alder et de polycyclisation anionique.
Étude des effets stéréo-électroniques dans les groupements fonctionnels et les réactions organiques. Importance des liaisons courbes (tau) en chimie organique.
P. DESLONGCHAMPS. Stereochemistry of E’ and E” Decarboxylative-Dehydration Reactions and the Bent Bond / Antiperiplanar Hypothesis Orbital Model. Tetrahedron. Submitted in May 2021.
G. DESLONGCHAMPS, N. VATCHER, P. DESLONGCHAMPS. Revisiting the Conformational Analysis of Unsaturated Organic Compounds Using the Bent Bond / Antiperiplanar Hypothesis. Tetrahedron 92, 132249 (July 16th, 2021).
P. DESLONGCHAMPS. Bent Bond / Antiperiplanar Hypothesis and Antiaromatic, Aromatic and Nonaromatic Molecules. Tetrahedron 89, 132161 (June 4th, 2021)
P. DESLONGCHAMPS. The Conformation and Reactivity of Butadiene and the Bent Bond / Antiperiplanar Hypothesis Orbital Model. Tetrahedron 85, 132060 (April 9th, 2021).
P. DESLONGCHAMPS. The Thermal Reactions of Naphthalene and Azulene. An Analysis through the Bent Bond and Antiperiplanar Hypothesis Orbital Model. Tetrahedron 82, 131956 (Feb. 26th, 2021).
L. OLIVER, S. RAGAM, P. DESLONGCHAMPS, J.M. WHITE, A. HANCOCK, S. BRYDON. Application of the Variable Oxygen Probe to Derivatives of 2,6-Dimethyltetrahydropyran-4-ol: Evidence for Through-Bond nO-sCC-s*CO Interactions. Aust. J. Chem. 03/08/2020, pp. 1-8 https://doi.org/10.1071/CH20149.
P. DESLONGCHAMPS. The Bent Bond / Antiperiplanar Hypothesis and the Thermal Rearrangement of Cyclopropyl Halides and Tosylates. Tetrahedron 76, 131416 (Sept. 4th, 2020).
G. DESLONGCHAMPS, P. DESLONGCHAMPS. The Bent Bond / Antiperiplanar Hypothesis and the Chemical Reactivity of Annulenes. J. Org. Chem. 85, 8645-8655 (2020).
J.-F. PARENT, G. DESLONGCHAMPS, P. DESLONGCHAMPS. The Bent Bond / Antiperiplanar Hypothesis: Modulating the Reactivity and the Selectivity in the Glycosylation of Bicyclic Pyranoside Models. J. Org. Chem. 85, 4220-4236 (2020).
J.-F. PARENT, X. BERTRAND, G. DESLONGCHAMPS, P. DESLONGCHAMPS. Applying the bent bond / antiperiplanar hypothesis to the stereoselective glycosylation of bicyclic furanosides. J. Org. Chem. 85, 758-773 (2020).